廈門(mén)大學(xué)化學(xué)系導(dǎo)師：萬(wàn)惠霖 正文

　　姓名： 萬(wàn)惠霖
　　性別： 男
　　出生年月：1938年11月
　　職務(wù)：教授
　　所屬類別：中國(guó)科學(xué)院院士
　　研究方向：催化化學(xué)
　　E-mail：
　　通信地址：廈門(mén)大學(xué)化學(xué)系 
　　郵編：361005
　　
　　個(gè)人中文簡(jiǎn)介
　　1938年11月生于湖北武漢。廈門(mén)大學(xué)化學(xué)系物理化學(xué)專業(yè)畢業(yè)(1962)和該專業(yè)催化理論方向研究生畢 (1966)，后留校教至今。期間曾作為訪問(wèn)學(xué)者在美國(guó)MIT化學(xué)系研究年余(1982～1983)。先后任廈門(mén)大學(xué)化學(xué)系教授(1987～)、系主任(1991～1996)、固體表面物理化學(xué)國(guó)家重點(diǎn)實(shí)驗(yàn)室主任和化學(xué)化工學(xué)院院長(zhǎng)(1996～2003)，中國(guó)化學(xué)會(huì)常務(wù)理事、中國(guó)科學(xué)院化學(xué)部常委、教育部科技委化學(xué)部主任和化學(xué)教學(xué)分指導(dǎo)委員會(huì)副主任、國(guó)務(wù)院學(xué)科評(píng)議組成員，廈門(mén)大學(xué)理工科和固體表面物理化學(xué)國(guó)家重點(diǎn)實(shí)驗(yàn)室學(xué)術(shù)委員會(huì)主任。60年代初就參與配位催化的基礎(chǔ)研究，后來(lái)又在專著中詳細(xì)闡述了配位催化原理。80年代初，對(duì)固氮酶幾種重要底物多核絡(luò)合方式的量子化學(xué)計(jì)算為固氮酶活性中心模型的優(yōu)化提供了重要依據(jù)。90年代初主持輕質(zhì)烷烴臨氧定向轉(zhuǎn)化的研究以來(lái)，在甲烷氧化偶聯(lián)含氟催化劑的結(jié)構(gòu)、酸堿性與催化性能關(guān)系，特別在活性氧物種及其反應(yīng)性能的原位光譜表征等方面取得了系統(tǒng)的創(chuàng)新性成果，對(duì)形成有關(guān)催化劑的設(shè)計(jì)構(gòu)思和發(fā)展有關(guān)新概念具有重要的學(xué)術(shù)意義。近年來(lái)，萬(wàn)惠霖主持的課題組基于對(duì)負(fù)載型貴金屬催化劑上甲烷部分氧化(POM)反應(yīng)機(jī)理的深入研究，提出其機(jī)理差異源于催化劑表面晶格氧物種濃度差異的具有相當(dāng)普適性的結(jié)論，發(fā)現(xiàn)并闡明La2O3表面激光誘導(dǎo)的O22-形成及其機(jī)理，采用小簇模型，對(duì)甲烷和丙烷在氧化鉬上的活化進(jìn)行了系統(tǒng)理論研究。與同事合作在國(guó)內(nèi)外刊物上發(fā)表論文350多篇，出版專著1部，獲國(guó)家自然科學(xué)三等獎(jiǎng)2項(xiàng)，國(guó)家教育部科技進(jìn)步一等獎(jiǎng)2項(xiàng)和二等獎(jiǎng)3項(xiàng)，獲發(fā)明專利15項(xiàng)。1997年當(dāng)選為中國(guó)科學(xué)院院士。
　　
　　 個(gè)人英文簡(jiǎn)介
　　 Born in November, 1938, Wuhan, Hubei Province. Completed his graduate study in early 1966 from the Department of Chemistry, Xiamen University. Professor, Director of the State Key Laboratory of Physical Chemistry of Solid Surface, and Dean of the College of　Chemistry and Chemical Engineering, Xiamen University (1996-2003). Chairman of the Academic Committee, the Faculties of Science and Engineering, Xiamen University, and the　State Key Laboratory of Physical Chemistry of Solid Surfaces.
Wan joined the Department of Chemistry, Xiamen Univeristy in 1966. He has been a principal participant in research on the theory of coordination catalysis and chemical　 modeling of biological nitrogen fixation. He has also successfully engaged in　 fundamental research on selective (amm)oxidation of propylene and quantum chemistry in catalysis. Since early 1990s, he has led an extensive study on the oxidative coupling of methane (OCM) and oxidative conversion of light alkanes (C2-C4) and made important achievements in the field. He and his research group developed a series of fluoride-containing rare-earth-alkaline-earth-oxide-based catalysts with good and excellent catalytic performance in OCM and oxidative dehydrogenation (ODH) of ethane and propane, and expounded the　nature of the promoter action of fluorides in the catalysts. On the basis of these　studies, he has put forward the principle of structure-directed constituent selection for OCM and ODH of ethane, and illustrated that neither surface basicity, nor p-type　conductivity is always a requisite attribute for a good OCM catalyst. He and his　colleagues have successfully used in situ spectroscopic methods to characterize surface　oxygen adspecies under the OCM reaction conditions over the fluoride-containing OCM　catalysts and obtained direct spectroscopic evidence for the superoxide adspecies being　an active oxygen adspecies for OCM reaction. Part of their research work on the fluoride- containing catalysts was reported by the Chemical and Engineering News (C&EN) in1994.Recently, Wan and his research group proposed and generalized the factors determining　the mechanism of partial oxidation of methane (POM) to synthesis gas over the supported noble metal catalysts based upon a systematic study on the reaction using in situ time-resolved FTIR and in situ Raman spectroscopies; discovered the laser induced peroxide(O22-) formation on the surface of the La2O3 under O2 and proposed the related　mechanism; and carried out a theoretical study on the activation mechanisms of methane　and propane and found that the H abstraction mechanism is the most feasible reactionpathway.As author or coauthor, he has published one book and more than 350 research papers in domestic and international journals，and won two National Awards for Natural Science(3rd prize)and a few prizes by the State Ministry of Education. He has also held 15
national patents of invention.He was elected Member of the Chinese Academy of Sciences in 1997.
　　
　　代表性成果
　　論文發(fā)表：
　　(1) An efficient synthesis of helical mesoporous silica nanorods，CHEMISTRY LETTERS 2006, 35, (2), 190-191.，2006年02月
　　(2) Oxidative dehydrogenation of ethane to ethylene over LiCl/SO42-ZrO2 catalyst，CHINESE JOURNAL OF CATALYSIS 2006, 27, (1), 79-85，2006年01月
　　(3) Preparation of MoVTe(Sb)Nb mixed oxide catalysts using a slurry method for selective oxidative dehydrogenation of ethane，JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 2005, 240, (1-2), 191-196.，2005年10月
　　 (4) MCM41 and silica supported MoVTe mixed oxide catalysts for direct oxidation of propane to acrolein，Applied Catalysis A-General 2005, 293, 49-55.，2005年09月
　　 (5) Oscillations of partial oxidation of methane over H-ZSM-5 supported rhodium catalyst，JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 2005, 239, (1-2), 193-200.，2005年09月
　　 (6) Effect of Te on selective oxidation of propane to acrolein over MoPO/SiO2 catalyst，CHINESE JOURNAL OF CATALYSIS 2005, 26, (6), 497-502.，2005年06月
　　 (7) Mechanisms of initial propane activation on molybdenum oxides: A density functional theory study，JOURNAL OF PHYSICAL CHEMISTRY B 2005, 109, (13), 6416-6421.，2005年04月
　　 (8) Mechanisms of methane activation and transformation on molybdenum oxide based catalysts，JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 2005, 127, (11), 3989-3996.，2005年03月
　　 (9) Partial oxidation of methane to hydrogen and carbon monoxide over a Ni/TiO2 catalyst，JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 2005, 226, (1), 41-48.，2005年02月
　　 (10) Preparation of Zr-promoted nano-NiO catalyst and its catalytic performance for oxidative dehydrogenation of ethane to ethylene，CHINESE JOURNAL OF CATALYSIS 2005, 26, (2), 148-152.，2005年02月
　　 (11) Fabrication of zeolite A rods with irregular macropores by self-assembly of zeolite A microcrystals using microwave-assisted hydrothermal synthesis，CHINESE JOURNAL OF CHEMISTRY 2004, 22, (12), 1454-1455.，2004年12月
　　 (12) Investigation of catalysis mechanism for oxidative dehydrogenation of ethane over cobalt-based catalysts，ACTA CHIMICA SINICA 2004, 62, (18), 1760-1764.，2004年09月
　　 (13) Study on structures and performances of MoVTeO/SiO2 catalysts for selective oxidation of propane to acrolein，ACTA CHIMICA SINICA 2004, 62, (18), 1701-1705.，2004年09月
　　 (14) In situ time-resolved FTIR and Raman characterizations of the partial oxidation of methane to synthesis gas over Ir/SiO2 catalyst，ACTA CHIMICA SINICA 2004, 62, (18), 1853-1857.，2004年09月
　　 (15) Partial oxidation of methane to H2 and CO over Rh/SiO2 and Ru/SiO2 catalysts，JOURNAL OF CATALYSIS 2004, 226, (2), 247-259.，2004年09月
　　 (16) Laser-induced formation of metal-peroxide linkages on the surface of lanthanum sesquioxide under oxygen，ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 43(8)975，2004年02月
　　 (17) Effect of Ag promoter on redox properties and catalytic performance of Ag-Mo-P-O catalysts for oxidative dehydrogenation of propane，APPLIED SURFACE SCIENCE 220 (1-4): 117-124 DEC 30 2003，2003年12月
　　 (18) Density functional calculations on the binding of dinitrogen to the FeFe cofactor in Fe-only nitrogenase: FeFeCo(mu(6)-N-2) as intermediate in nitrogen fixation，INORGANIC CHEMISTRY 42 (22): 6986-6988 NOV 3 2003，2003年11月
　　 (19) Density functional characterization of N-2 dissociation on the step of ruthenium clusters，JOURNAL OF CHEMICAL PHYSICS 119 (17): 9178-9182 NOV 1 2003，2003年11月
　　 (20) Effect of promoter Ce on silver-molybdenum-phosphate catalysts for selective oxidation of propane to acrolein，JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 200 (1-2): 291-300 JUN 2 2003，2003年06月
　　 (21) Selective oxidation of propane to acrolein over Ce-doped Ag-Mo-P-O catalysts: influence of Ce promoter，CATALYSIS LETTERS 87 (3-4): 229-234 APR 2003，2003年04月
　　 (22) Studies on VPO/SiO2 catalyst for selective oxidation of propane，CHINESE JOURNAL OF CATALYSIS 24 (2): 87-92 FEB 2003，2003年02月
　　 (23) Activation of methane to syngas over a Ni/TiO2 catalyst，APPLIED CATALYSIS A-GENERAL 239 (1-2): 43-58 JAN 30 2003，2003年01月
　　 (24) Comparative study on the mechanisms of partial oxidation of methane to syngas over rhodium supported on SiO2 and gamma-Al2O3，TOPICS IN CATALYSIS 22 (1-2): 87-93 JAN 2003，2003年01月
　　
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